Ethylene glycol (C2H6O2) is molecular compound that is used in many commercial anti-freezes. An aqueous solution of ethylene glycol is used in vehicle radiators to prevent the water in the radiator from freezing by lowering its freezing point. Calculate the freezing point of a solution of 400g of ethylene glycol in 500g of water.
Kf (H2O) = -1.86 o C/m
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Answer:
The freezing point of this solution will be - 13.32°C.
Explanation:
The freezing point depression of the solution is given by the equation as follows:
Δ
Where we have Δ = the lowering of the freezing point
= cryoscopic constant = 1.86 K Kg/mol and m = the molality
First, we will find out the moles of ethylene glycol solution in water by the following given formula:
No. of moles of ethylene glycol = mass of ethylene glycol / molar mass of ethylene glycol
= 2×12g + 6×1g + 2×16g = 62g
No. of moles =
Now, we find out the molality,
molality = no of moles of the given solute / the total mass of given solution in Kg
Total mass of the solution = 400g + 500g = 900g = 0.9 Kg
Molality =
Now, we have the freezing point lowering as:
Δ
Δ = 1.86 × 7.16 = 13.3176
Now we know that the water freezing point is 0° C
Therefore the freezing point = 0°C - 13.3176°C = -13.3176°C
Hence we get the final answer to be - 13.32°C.