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Example 5.21 Calculate the weight of MnO2 required to
produce 1.50 L of chlorine at 27°C and 1.50 atm pressure according to
the following equation :
Mno2 + 4HCI - MnCl2 + 2H2O + CI2
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Answer:
95.7 g
Explanation:
Mno2 + 4HCI → MnCl2 + 2H2O + CI2
observe the co-efficients....
1 mole MnO2 → 1 mole Cl2
(x/55+2×16) → 22.4 L ( mole = W/M)
x = 1948.8 g
means....at STP...
22.4 L of Cl2 → 1949g MnO2
now....at... T' = 27°C ; P = 1.5atm ; V = 1.5L ; V' = ?
since PV/T = P'V'/T'
V' = PVT'/P'T'
hence V' = 1 × 1.5 × 300/1.5×273 = 1.1L
now....
1.1 L of Cl2 → ? g MnO2
MnO2 = 1.1 × 1949/22.4 = 95.7g
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