Example 7 :
A solid is made of two elements X and Y. Atoms X are in fcc arrangement and Y atoms occupy
all the octahedral sites and alternate tetrahedral sites. What is the formula of compound?
Solution :
Na 8
v
Atoms of X forming fcc lattice means they occupy 8 corners and 6 face centres hence number
of atoms = 4
Tetrahedral sites = 8
Number of Y atoms = 4
Octahedral sites = 4
Number of Y atoms = 4
.:. Total number of Y atoms = 8
X:Y
4:8 or 1: 2. Hence formula of compound is XY2
Answers
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Atoms of X forming fcc lattice means they occupy 8 corners and 6 face centres .
∴ Total number of Y atoms = 8
∴ X : Y = 4:8 = 1:2 .
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