examples of self exchange and cross exchange reactions
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Self-exchange
Outer sphere electron transfer can occur between chemical species that are identical except for their oxidation state. This process is termed self-exchange. An example is the degenerate reaction between the tetrahedral ions permanganate and manganate: [MnO4]− + [Mn*O4]2− → [MnO4]2− + [Mn*O4]
Cross reactions entail partners that differ by more than their oxidation states. One example (of many thousands) is the reduction of permanganate by iodide to form iodine and, again, manganate.
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