Chemistry, asked by saikethansaikethan, 9 months ago

explain debroglie's equation.If anybody explain this I will mark that answer as brainliest answer​

Answers

Answered by sanskarbansalbtp
0

Answer:

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debroglie eqn is too long

you can see it here

Explanation:

What is de Broglie Equation?

The de Broglie equation is one of the equations that is commonly used to define the wave properties of matter. It basically describes the wave nature of the electron.

Electromagnetic radiation, exhibit dual nature of a particle (having a momentum) and wave (expressed in frequency, wavelength). Microscopic particle-like electrons also proved to possess this dual nature property.

Louis de Broglie in his thesis suggested that any moving particle, whether microscopic or macroscopic will be associated with a wave character. It was called ‘Matter Waves’. He further proposed a relation between the velocity and momentum of a particle with the wavelength if the particle had to behave as a wave.

Particle and wave nature of matter, however, looked contradictory as it was not possible to prove the existence of both properties in any single experiment. This is because of the fact that every experiment is normally based on some principle and results related to the principle are only reflected in that experiment and not the other.  

Nonetheless, both the properties are necessary to understand or describe the matter completely. Hence, particles and wave nature of matter are actually ‘complimentary’ to each other. It is not necessary for both to be present at the same time though. The significance of de Broglie relation is that it is more useful to microscopic, fundamental particles like electron.

de Broglie Equation Derivation and de Broglie Wavelength

Very low mass particles moving at speed less than that of light behaves like a particle and wave. De Broglie derived an expression relating the mass of such smaller particles and its wavelength.

Plank’s quantum theory relates the energy of an electromagnetic wave to its wavelength or frequency.

  E  = hν  =\frac{hc}{\lambda }=  

λ

hc

​  

    …….(1)

Einstein related the energy of particle matter to its mass and velocity, as  E = mc2……..(2)

As the smaller particle exhibits dual nature, and energy being the same, de Broglie equated both these relations for the particle moving with velocity ‘v’ as,

E = =\frac{hc}{\lambda }=m{{v}^{2}}:=  

λ

hc

​  

=mv  

2

:     Then, \frac{h}{\lambda }=mv  

λ

h

​  

=mv or \lambda =\frac{h}{mv}=\frac{h}{\text{momentum}}:λ=  

mv

h

​  

=  

momentum

h

​  

: where ‘h’ is the Plank’s constant.

This equation relating the momentum of a particle with its wavelength is de Broglie equation and the wavelength calculated using this relation is de Broglie wavelength.

Relation Between de Broglie Equation and Bohr’s Hypothesis of Atom

Bohr postulated that angular momentum of an electron revolving around the nucleus as quantized. Hence, the angular momentum will only be an integral multiple of a constant value and suggested the following expression.

Angular momentum of electron in orbit =  mvr =\frac{nh}{2\pi }:=  

nh

​  

: where ‘n’ is an integer with values of 1,2,3..  

Bohr did not give any reason for such a proposal.  

But, de Broglie equation gives a scientific validation for such an imaginative proposal.

By, de Broglie, equation \lambda =\frac{h}{mv}λ=  

mv

h

​  

   or    mv=\frac{h}{\lambda }mv=  

λ

h

​  

   

The electron wave in an orbit must be in phase and so,  

Circumference of an orbit = integral multiple of the wavelength.

2\pi r=n\lambda2πr=nλ   or \frac{1}{\lambda }=\frac{n}{2\pi r}  

λ

1

​  

=  

2πr

n

​  

 

Substituting for wave length, in the De Broglie equation,   mv=\frac{nh}{2\pi r}mv=  

2πr

nh

​  

 or mvr=n\times \frac{h}{2\pi }mvr=n×  

h

​  

 

Hence the angular momentum of electron (mvr) is an integral multiple of a constant \left( \frac{h}{2\pi } \right)(  

h

​  

)

Solved Problems on de Broglie Equation

Answered by BrainlyEmpire
1

Answer:

hello mate..

Explanation:

The de Broglie equation is an equation used to describe the wave properties of matter, specifically, the wave nature of the electron: λ = h/mv, where λ is wavelength, h is Planck's constant, m is the mass of a particle, moving at a velocity v. de Broglie suggested that particles can exhibit properties of waves.

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