explain elevation in boiling point
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Answer:
Boiling-point elevation describes the phenomenon that the boiling point of a liquid (a solvent) will be higher when another compound is added, meaning that a solution has a higher boiling point than a pure solvent. This happens whenever a non-volatile solute, such as a salt, is added to a pure solvent, such as water.
What is Boiling Point Elevation?
Boiling point elevation refers to the increase in the boiling point of a solvent upon the addition of a solute. When a non-volatile solute is added to a solvent, the resulting solution has a higher boiling point than that of the pure solvent. For example, the boiling point of a solution of sodium chloride (salt) and water is greater than that of pure water.
Boiling point elevation is a colligative property of matter, i.e. it is dependent on the solute-to-solvent ratio but not on the solute’s identity. This implies that the elevation in the boiling point of a solution depends on the amount of solute added to it. The greater the concentration of solute in the solution, the greater the boiling point elevation.
Why Does Boiling Point Elevation Occur?
The boiling point of a liquid is the temperature at which its vapour pressure is equal to the pressure of its surrounding environment. Non-volatile substances do not readily undergo evaporation and have very low vapour pressures (assumed to be zero). When a non-volatile solute is added to a solvent, the vapour pressure of the resulting solution is lower than that of the pure solvent.
Therefore, a greater amount of heat must be supplied to the solution for it to boil. This increase in the boiling point of the solution is the boiling point elevation. An increase in the concentration of added solute is accompanied by a further decrease in the vapour pressure of the solution and further elevation in the boiling point of the solution.
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