Explain pseudo first order reaction with suitable example.
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A Pseudo first-order reaction can be defined as a second-order or bimolecular reaction that is made to behave like a first-order reaction. This reaction occurs when one reacting material is present in great excess or is maintained at a constant concentration compared with the other substance.
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- A Pseudo first-order reaction can be defined as a second-order or bimolecular reaction that is made to behave like a first-order reaction. This reaction occurs when one reacting material is present in great excess or is maintained at a constant concentration compared with the other substance.
- Consider the hydrolysis of ethyl acetate, during the hydrolysis, the concentration of ethyl acetate is 0.02 mol/L whereas the amount of water is 20 mol/L as the process of hydrolysis involves a large amount of water. Let us say, the process of hydrolysis attains completion in time t.
- The reaction can be represented as
- CH3COOC2H5 + H2O —–> CH3COOH + C2H5OH
- (ethyl acetate) (Water) (Acetic acid) (ethyl alcohol)
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