explain sp3 d hybridization
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Answer:
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Combination of 1s, 3p and 1d orbital result in the formation of sp3d orbital in which three lobes are oriented towards the corners of a triangle and the other lie perpendicular to them to minimize the repulsions.
In sp3d hybridization, one ‘s’, three ‘p’ and one ‘d’ orbitals of almost equal energy intermix to give five identical and degenerate hybrid orbitals, which are arranged in trigonal bipyramidal symmetry.
Among them, three are arranged in trigonal plane and the remaining two orbitals are present above and below the trigonal plane at right angles. The sp3d hybrid orbitals have 20% ‘s’, 60% ‘p’ and 20% ‘d’ characters.
Example: PF5
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Answer:
in sp3 d hybridization
5 bonds are there
for example SF4
when we find no.of bonds it comes out to be 5
like S=4
F=7*4 as 4F are there
so now add we get
4+28=32
now divide 32 with 8 we get 4 bonds + 1 lone pair which makes total 5 bonds
the condition for this hybridization is
(a)4 bond pair +1 lone pair
(b)3 bond pair+ 2 lone pair
(c)2 bond pair + 3 lone pair
and the shape formed is
trigonal bipyramidal(5 bond pair+0lone pair)
irregular tetrahedron(in a)
T shape (in b)
linear(in c)