explain stability of carbocation on the basis of hyperconjucation
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Answer:
Carbocations Are Stabilized By Neighboring Carbon Atoms. ... The second, (and theoretically more satisfactory explanation) is hyperconjugation, which invokes stabilization through donation of the electrons in C-H sigma bonds to the empty p orbital of the carbocation.
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Answer:
The stability of carbocations increases as we go from primary to secondary to tertiary carbons. There’s two answers as to why this is. The age-old answer that is still passed around in many introductory textbooks points to carbons (alkyl groups in particular) as being “electron-releasing” groups through inductive effects. That is, a carbon (electronegativity 2.5) connected to hydrogen (electronegativity 2.2) will be electron rich, and can donate some of those electrons to the neighboring carbocation. In other words, the neighboring carbon pays the carbocation with electrons it steals from the hydrogens. The second, (and theoretically more satisfactory explanation) is hyperconjugation, which invokes stabilization through donation of the electrons in C-H sigma bonds to the empty p orbital of the carbocation.
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