Explain structural isomerism with suitable illustrations
Answers
Answer:
Explanation:
In structural isomerism, the atoms are arranged in a completely different order. This is easier to see with specific examples.
What follows looks at some of the ways that structural isomers can arise. The names of the various forms of structural isomerism probably don't matter all that much, but you must be aware of the different possibilities when you come to draw isomers.
Types of structural isomerism
Chain isomerism
These isomers arise because of the possibility of branching in carbon chains. For example, there are two isomers of butane, C4H10. In one of them, the carbon atoms lie in a "straight chain" whereas in the other the chain is branched.
Pentane, C5H12, has three chain isomers. If you think you can find any others, they are simply twisted versions of the ones below. If in doubt make some models.
Position isomerism
In position isomerism, the basic carbon skeleton remains unchanged, but important groups are moved around on that skeleton.
For example, there are two structural isomers with the molecular formula C3H7Br. In one of them the bromine atom is on the end of the chain, whereas in the other it's attached in the middle.
If you made a model, there is no way that you could twist one molecule to turn it into the other one. You would have to break the bromine off the end and re-attach it in the middle. At the same time, you would have to move a hydrogen from the middle to the end.
Another similar example occurs in alcohols such as C4H9OH
These are the only two possibilities provided you keep to a four carbon chain, but there is no reason why you should do that. You can easily have a mixture of chain isomerism and position isomerism - you aren't restricted to one or the other.
So two other isomers of butanol are:
You can also get position isomers on benzene rings. Consider the molecular formula C7H7Cl. There are four different isomers you could make depending on the position of the chlorine atom. In one case it is attached to the side-group carbon atom, and then there are three other possible positions it could have around the ring - next to the CH3 group, next-but-one to the CH3 group, or opposite the CH3 group.
Functional group isomerism
In this variety of structural isomerism, the isomers contain different functional groups - that is, they belong to different families of compounds (different homologous series).
For example, a molecular formula C3H6O could be either propanal (an aldehyde) or propanone (a ketone).
There are other possibilities as well for this same molecular formula - for example, you could have a carbon-carbon double bond (an alkene) and an -OH group (an alcohol) in the same molecule.
Another common example is illustrated by the molecular formula C3H6O2. Amongst the several structural isomers of this are propanoic acid (a carboxylic acid) and methyl ethanoate (an ester).
Answer:
The phenomenon in which different compounds having the same functional groups at different positions on the parent chain is known as position isomerism.
For example,
But-2-ene [CH_3 -CH=CH-CH_3]
and but-1-ene (CH_2 = CH – CH_2 - CH_3] are position isomers of each other as they have the same molecular formula C_4 H_8 and the same carbon skeleton but the double bonds are located at different positions.