Explain the following reactions (write only chemical equations): (i) Acetylation (ii) Friedel-Crafts reaction
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Answer:
i)Acetylation
Explanation:
Option no. i) is the right one
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Acetylation and Friedel-crafts reaction
Explanation:
- Acetylation is a type of chemical reaction that involves the replacement of a hydrogen atom belonging to an alcohol group with an acetyl group.
- Example of Acetylation is reaction of salicylic acid with acetic anhydride to give acetylsalicylic acid (aspirin) and acetic acid.
- Reaction involved in acetylation is -
salicylic acid + acetic anhydride → acetylsalicylic acid + acetic acid
- Friedel crafts reaction is a type of organic reaction which involves electrophilic aromatic substitution and used for attaching substituents to aromatic rings. It is of two types - alkylation and acylation reactions.
- Friedel Crafts alkylation involves addition of alkyl group to a aromatic ring by replacing aromatic proton.
C₆H₆ + CH₃Cl + AlCl₃ → C₆H₅CH₃
- Friedel Crafts Acylation involves replacement of aromatic proton with a acyl group.
C₆H₆ + CH₃COCl + AlCl₃ → C₆H₅COCH₃ + HCl
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