Explain the following terms with suitable examples: (i) Schottky defect (ii) Frenkel defect (iii) Interstitials and (iv) F-centres
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(i) Schottky defect : When an atom or ion is missing from its normal site, a lattice vacancy (Schottky defect) is created. Equal number of cations and anions are missing in ionic solids, e.g., in NaCl, there is Schottky defect.
(ii) Frenkel defect : When an atom or ion occupies interstitial position instead of normal position, it leads to Frenkel defect. In AgCl, Frenkel defect is found.
(iii) Interstitials : The vacant positions in the crystal lattice are called interstitials or voids, e.g., transition metals have interstitials.
(iv) F-centres : Electrons trapped in anion vacancies are called F-centres. If we heat NaCI in sodium vapours, the vacant position of anions are occupied by electrons forming F-centres.
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