explain the formation of PVC in with polymerization by addition method.
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Polymerization of chloroethene (vinyl chloride)
This is an example of addition polymerization. PVC is made by free-radical polymerization in suspension. The monomer (bp 259 K) is polymerized in aqueous dispersion at 325-350 K. Pressure (13 atm) is used to keep the monomer in a liquid phase.
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Polyvinyl chloride is produced in an addition polymerisation reaction using the chloroethene (vinyl chloride) monomer. This polymerisation reaction proceeds by a free-radical mechanism. Polyvinyl chloride is a white, rigid, quite brittle, solid.
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