Question

Explain the hybridization of Mg in Grigdnard reagent.

Answer 1

Answer:

Structures of the magnesium Grignard complexes CH3MgF, CH3MgMgF, CH3MgF(Mg), and CH3MgF(Mg-2) have been studied by ab initio methods of quantum chemistry, including self-consistent-field, many-body perturbation theory, and density functional theory techniques, Electronic distributions have been analyzed by means of natural bond orbital analysis. It has been found that magnesium atoms can be attached to the Grignard reagent CH3MgF, leading to a dimagnesium complex CH3MgF(Mg) and the trimagnesium species CH3MgF(Mg-2). The energy of the CH3MgF(Mg) complex is found to be lower than that of the previously known CH3MgMgF compound.

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Answer 2

Answer:

Haloalkanes and other compounds with the halogen atom bonded to either sp3-hybridized or sp2-hybridized carbon atoms (aryl and vinyl halides) react with magnesium metal to yield organ magnesium halides called Grignard reagents. Grignard reagents are usually prepared in diethyl ether (CH3CH2O─CH2CH3). An ether solvent is essential for the reaction. The French chemist Victor Grignard discovered this reaction in 1900, and it has been studied and used extensively ever since.

Grignard reagents form easily from 1°, 2°, and 3° alkyl halides, although their reactivities differ. Aryl and vinyl halides react somewhat more slowly, and the cyclic ether tetrahydrofuran (THF) is required to prepare Grignard reagents of these compounds. The higher boiling point of the cyclic ether provides more vigorous reaction conditions, but the rate of the reaction also increases because THF solvates the Grignard reagent better than diethyl ether.

Haloalkanes and aryl and vinyl halides react with magnesium metal to yield organ magnesium halides called Grignard reagents. An ether solvent, usually diethyl ether, is required for preparation of Grignard reagents. The French chemist Victor Grignard discovered this reaction over a century ago in 1900. Grignard reagents are powerful tools for the synthesis of alcohols.

Explanation:

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