explain the synthesis of phosphine
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Industrially it can be made by the reaction of white phosphorus with sodium or potassium hydroxide, producing potassium or sodium hypophosphite as a by-product. 3 KOH + P4 + 3 H2O → 3 KH2PO2 + PH3. Alternatively the acid-catalyzed disproportioning of white phosphorus yields phosphoric acid and phosphine.
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The methods most widely used for the synthesis of phosphine include the reaction organometallic
compounds with halophosphines , the reaction of metal phosphides with alkyl halides, the reduction of other phosphorus compounds and the hydrosphosphinathion
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