Explain the term chain reaction with a suitable example
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The reaction H2 + Br2 → 2 HBr proceeds by the following mechanism:
Initiation
Br2 → 2 Br• (thermal) or Br2 + hν → 2 Br• (photochemical)each Br atom is a free radical, indicated by the symbol « • » representing an unpaired electron.
Propagation (here a cycle of two steps)
Br• + H2 → HBr + H•H• + Br2 → HBr + Br•the sum of these two steps corresponds to the overall reaction H2 + Br2 → 2 HBr, with catalysis by Br• which participates in the first step and is regenerated in the second step.
Retardation (inhibition)
H• + HBr → H2 + Br•this step is specific to this example, and corresponds to the first propagation step in reverse.
Termination 2 Br• → Br2
recombination of two radicals, corresponding in this example to initiation in reverse.
The reaction H2 + Br2 → 2 HBr proceeds by the following mechanism:
Initiation
Br2 → 2 Br• (thermal) or Br2 + hν → 2 Br• (photochemical)each Br atom is a free radical, indicated by the symbol « • » representing an unpaired electron.
Propagation (here a cycle of two steps)
Br• + H2 → HBr + H•H• + Br2 → HBr + Br•the sum of these two steps corresponds to the overall reaction H2 + Br2 → 2 HBr, with catalysis by Br• which participates in the first step and is regenerated in the second step.
Retardation (inhibition)
H• + HBr → H2 + Br•this step is specific to this example, and corresponds to the first propagation step in reverse.
Termination 2 Br• → Br2
recombination of two radicals, corresponding in this example to initiation in reverse.
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