explain the use of 12 crown 4 in separation of alkali metals
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The formation of 12-crown-4 to the amino group Pittsburg compound B (PiB) generated in a simple two step process to generate a conjugate PiB-C (1) , which was shown to change the zeta potential of A-bita fibrils (14CC15892). The synthesis of bis( benzo-21-crown-7)- based "wheel" prepared and then threaded with an anthracene-capped dialkyl salt based "axle" which is then capped with phenyl isocyanate to lock and generate {3} rotaxanes, which were then photolyzed to produce a poly(3)rotaxane VOA the reversible photocyclodimerization of the terminal 9- anthryl moieties (14CC14105).
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