Question

Explain the variation of ionization enthalpy in a period and in a group.

Answer 1

Answer:

Explanation:

Moving left to right within a period or upward within a group, the first ionization energy generally increases. As the atomic radius decreases, it becomes harder to remove an electron that is closer to a more positively charged nucleus. They experience a weaker attraction to the positive charge of the nucleus.

Answer 2

Explanation:

Moving from left to right across the periodic table, the ionization energy for an atom increases. We can explain this by considering the nuclear charge of the atom. The more protons in the nucleus, the stronger the attraction of the nucleus to electrons. This stronger attraction makes it more difficult to remove electrons.

Within a group, the ionization energy decreases as the size of the atom gets larger. On the graph, we see that the ionization energy increases as we go up the group to smaller atoms. In this situation, the first electron removed is farther from the nucleus as the atomic number (number of protons) increases. Being farther away from the positive attraction makes it easier for that electron to be pulled off.

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