explain vacancy through aliovalant cations
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Vacancies are created by the addition of impurities of aliovalent ions (that is, ions with oxidation state different from that of host ions) to an ionic solid. e.g. Consider a small amount of SrCl2 impurity added to NaCl during its crystallization. ... = +2) occupy some of the regular sites of Na+ host ions (O.S. = +1).
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