Chemistry, asked by chemongessimon573, 11 months ago

explain why hydrolysis of Ncl3 and Pcl3 yields diferet products

Answers

Answered by Brainly0786
30
In NCl3, nitrogen and chlorine have similar electronegativities resulting in non-polar bonds. Nitrogen doesn’t have empty d-orbitals so the hydrolysis takes place with the donation of lone pair of electron by nitrogen to the hydrogen atom of water.

NCl3 + H2O → NH3 + 3HOCl

In PCl3, phosphorous is less electronegative than chlorine so, they form a polar bond. So, the positive polar charge on phosphorous attacks the lone pair of electrons on water molecule to give different products.

PCl3 + 3H2O → H3PO3 + 3HCl

Answered by Anonymous
6

Hello Mate,

In NCl3, nitrogen and chlorine have similar electronegativities resulting in non-polar bonds. Nitrogen doesn’t have empty d-orbitals so the hydrolysis takes place with the donation of lone pair of electron by nitrogen to the hydrogen atom of water.

NCl3 + H2O → NH3 + 3HOCl

Hope this helps you

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