explain why hydrolysis of Ncl3 and Pcl3 yields diferet products
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Answered by
30
In NCl3, nitrogen and chlorine have similar electronegativities resulting in non-polar bonds. Nitrogen doesn’t have empty d-orbitals so the hydrolysis takes place with the donation of lone pair of electron by nitrogen to the hydrogen atom of water.
NCl3 + H2O → NH3 + 3HOCl
In PCl3, phosphorous is less electronegative than chlorine so, they form a polar bond. So, the positive polar charge on phosphorous attacks the lone pair of electrons on water molecule to give different products.
PCl3 + 3H2O → H3PO3 + 3HCl
NCl3 + H2O → NH3 + 3HOCl
In PCl3, phosphorous is less electronegative than chlorine so, they form a polar bond. So, the positive polar charge on phosphorous attacks the lone pair of electrons on water molecule to give different products.
PCl3 + 3H2O → H3PO3 + 3HCl
Answered by
6
Hello Mate,
In NCl3, nitrogen and chlorine have similar electronegativities resulting in non-polar bonds. Nitrogen doesn’t have empty d-orbitals so the hydrolysis takes place with the donation of lone pair of electron by nitrogen to the hydrogen atom of water.
NCl3 + H2O → NH3 + 3HOCl
Hope this helps you
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