Explain why: (i) Ethylamine is soluble in water but aniline is not. (ii) Aniline does not undergo Friedel Crafts reaction. (iii) Aniline is acetylated before bromination.
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1. it makes intermolecular bonds with hydrogen in water
2. It is a very strong base and forms salt on reacting with AlCl3. Due to which a net negative charge develops on nitrogen which deactivates further electrophilic substitution in benzene ring
3. In order to avoid its tribromoaline formation, it is acetylated first
2. It is a very strong base and forms salt on reacting with AlCl3. Due to which a net negative charge develops on nitrogen which deactivates further electrophilic substitution in benzene ring
3. In order to avoid its tribromoaline formation, it is acetylated first
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Explanation:
: (i) Ethylamine is soluble in water but aniline is not. (ii) Aniline does not undergo Friedel Crafts reaction. (iii) Aniline is acetylated before bromination.
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