Question

Explain why splitting of d orbitals in octahedral complex is exactly opposite ini that of tetrahedral

Answer 1

Answer:

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Explanation:

Therefore, the crystal field splitting diagram for tetrahedral complexes is the opposite of an octahedral diagram. The dx2−dy2 and dz2 orbitals should be equally low in energy because they exist between the ligand axis, allowing them to experience little repulsion. ... This maximizes repulsion and raises energy levels.

Answer 2

Splitting of d orbitals in octahedral complex is exactly opposite to that of tetrahedral

because of less repulsion experienced in tetrahedral compare to  Octahedral

Explanation:

• In octahedral complex, dxy , dyz and dzx are axial so these experience low repulsion and have low energy these are known as  t2g orbitals.

• In octahedral complex, the other two d orbital experience more repulsion and so these have high energy and are known as eg orbitals.

• In tetrahedral complex, dxy , dyz and dzx  experience more repulsion and have high energy these are known as  t2g orbitals.

• In tetrahedral complex, the other two d orbital experience less repulsion and so these have low energy and are known as eg orbitals.

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