Explains the different types of speed possessed by molecules
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There are basically three different types of molecular speed - Root mean square speed, average speed and most probable speed.
Vʳᵐˢ =
1) Root mean square speed
It is the square root of the mean of the squares of the speeds of different molecules.
Formula for Root mean square speed, 'v ':
2) Average Speed
It is the arithmetic mean of the speeds of different molecules.
Formula for average velocity, 'v ':
3) Most Probable Speed
It is the speed possessed by maximum number of molecules of the gas.
Formula for Most probable speed, 'v ':
where,
R = Gas constant
M = Molar mass of the gas
T = temperature of the gas.
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In kinetic theory of gas the velocity of molecules is expressed in the following three terms
➡️ (i) Root-mean square velocity or R.M.S. Velocity:
It may be defined as, “The square root of the mean value of the squares of the velocities of all molecules”. It is denoted by u. If V_1, V_2, V_3, \cdots V_n are the velocities for n molecules, then u = \sqrt{\dfrac{V_1^2 + V_2^2 + V_3^2 + \cdots + V_n^2}{n}}
➡️ (ii) The average velocity is the arithmetic mean of the velocities of all molecules. It is denoted by v and is given by the following equation:
v = \dfrac{(V_1 + V_2 + V_3 + \cdots V_n)}{n}[
Average velocity (v) = 0.9213 x R. M. S. velocity (u)
➡️ (iii) The most probable velocity is the velocity possessed by maximum number of molecules of the gas at a given temperature. It is denoted by \alpha and is given by the following equation:
\alpha = \dfrac{2RT}{M} = \dfrac{2RT}{mN} (since M= mN)
Or,
\alpha = \sqrt{\dfrac{2u}{3}}
These three velocities are related to each other as:
Y : v : \alpha = 1.0 : 0.9213 : 0.8177
\alpha = 1.0 : 1.128 : 1.224 so \alpha < v < u
Maxwell’s distribution of velocities.
Refer above ⬆️ ⬆️ in attachment.
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