extraction of iron aluminum and copper
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Extraction of Copper
The chief and important ore of copper from which the metal is most isolated is copper pyrites (CuFeS2). Froth floatation process is used for concentrating the ore. The powdered ore is suspended in water and after adding little pine oil is stirred by means of air. The sulphide ore particles come to the surface & gangue remains at the bottom is rejected.
1. Ores of Copper
Name of Ore
Formula of Ore
Copper glance or Chalcocite:
Cu2S
Chalcopyrites(copper pyrites):
Cu2S×Fe2S3
Cuprite
Cu2O
Malachite
[CuCO3.Cu(OH)2]
Azurite
[2CuCO3.Cu(OH)2]
2. Extraction of Metallic Copper
Concentration of the ore by froth floatation process:
Copper pyrites contains only (2-3)% of copper. The rest of the ore contains iron or sulphide, silica, silicious materials, sulphur, arsenic etc. as impurities. Froth flotation by Xanthate and pine oil. The froth is collected and dried when concentrated ore is obtained which contains 25-30% of Cu.
Roasting
Cu2S.Fe2S3 + O2 → Cu2S + 2FeS + SO2
Cu2S.Fe2S3 + 4O2 → Cu2S + 2FeO + 3SO2
2Cu2S + 3O2 → 2Cu2O + 2SO2
Cu2O + FeS → Cu2S + FeO
Smelting of the roasted ore in blast furnace: material required
Roasted ore
Lime stone
Coke (used as fuel)
Silica (used as flux)
Lime stone (used to remove excess silica)
Reactions occurring given as follows
2FeS + 3O2 → 2FeO + 2SO2
Cu2O + FeS → Cu2S + FeO