Extrapolate phase rule for the component which can exists in three states of matter.
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In thermodynamics, a component is one of a collection of chemically-independent constituents of a system. The number of components represents the minimum number of independent species necessary to define the composition of all phases of the system
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Phase rule:
The American physicist J. Willard Gibbs derived the phase rule, a law linking variables of a system in thermodynamic equilibrium.
The variables are the following:
- the number of chemical components C (pure compounds or elements),
- the number of phases P (forms of matter, such as solid, liquid, and gas—not necessarily of a single chemical component),
- the number of degrees of freedom F of intensive variables, such as temperature, pressure, and percentage composition.
Phase rule for a component which can exist in three states of matter:
- According to the phase rule, F = C - P + 2
- There is no degree of freedom for one component and three phases
- An example for such a case is ice floating in water with water vapor floating above it in a closed container.
- In the scenario, the temperature and pressure are both fixed at what is known as the triple point.
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