Facialㅤchirality.
Aㅤcyclophaneㅤconsistsㅤofㅤaromaticㅤunitsㅤ(typicallyㅤbenzeneㅤrings)ㅤandㅤaliphaticㅤchainsㅤthatㅤformㅤbridgesㅤbetweenㅤtwoㅤnon-adjacentㅤpositionsㅤofㅤtheㅤaromaticㅤrings.ㅤAsㅤshownㅤbelow,ㅤifㅤtheㅤbridgeㅤisㅤethyleneㅤ(-ㅤCH2-CH2-)ㅤandㅤtheㅤsubstitutionㅤpatternㅤisㅤpara,ㅤitㅤisㅤcalledㅤ[2.2]paracyclophane.ㅤForㅤsomeㅤkindsㅤofㅤ[2.2]paracyclophanes,ㅤenantiomersㅤcanㅤbeㅤisolatedㅤdependingㅤonㅤtheㅤsubstituentㅤconfigurationsㅤonㅤtheㅤaromaticㅤringsㅤgivenㅤthatㅤtheseㅤcannotㅤrotate.ㅤ
Brominationㅤofㅤ[2.2]paracyclophaneㅤwithㅤanㅤexcessㅤofㅤbromineㅤinㅤtheㅤpresenceㅤofㅤFeBr3ㅤresultsㅤinㅤdibrominationㅤonㅤeachㅤbenzeneㅤringㅤtoㅤgenerateㅤtetrabrominatedㅤproductsㅤFㅤ(F')ㅤandㅤGㅤ(G').ㅤNoteㅤthatㅤFㅤandㅤF'ㅤareㅤaㅤpairㅤofㅤenantiomers,ㅤwhileㅤGㅤandㅤG'ㅤareㅤidentical.ㅤByㅤaddingㅤtwoㅤequivalentsㅤofㅤn-BuLiㅤtoㅤaㅤsolutionㅤofㅤFㅤorㅤGㅤatㅤlowㅤtemperature,ㅤoneㅤofㅤtwoㅤbromo-substituentsㅤinㅤeachㅤbenzeneㅤunitㅤisㅤexchangedㅤtoㅤlithium,ㅤandㅤtheㅤsubsequentㅤadditionㅤofㅤanㅤexcessㅤofㅤDMFㅤleadsㅤtoㅤtheㅤformationㅤofㅤseveralㅤproducts.ㅤ
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ok but I didn't understand
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