Question

[Fe(CN)6]3– is an inner orbital complex whereas [FeF6]3– is an outer orbital complex.

Answer 1

Answer:

go through VBT concept of coordination chemistry hope u gonna get my answer

Answer 2

Inner orbital complexes-Coordination compounds having central metal atoms undergo hybridisation of d orbitals.

Outer orbital complexes-Coordination compounds having central metal atoms undergo hybridisation including d orbitals

Explanation:

Inner orbital complexes-

[Fe(CN)₆]³⁻ is an inner orbital complex,

Hybridization is d²sp³.It is paramagnetic in nature.

Outer orbital complexes-

The oxidation state of Fe is +3 and its coordination number is 6.

[FeF₆]³⁻ is paramagnetic due to the presence of unpaired electrons in the complex.hybridisation is sp³d².