find the value of h if (h+3)x^2-(11h+1)x+h-2(h-5)=0
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Solution
Let us consider reaction (i) and (ii)
Multiplying reaction (i) by 2, we get.
2H2(g)+2CO2(g)⇔2H2O(g)+2CO(g) ...(iv)
K
II
2000K
=K
2
2000K
=(4.40)2
Adding (iv) and (ii), we have
2CO2(g)⇔2CO+O2
K
III
2000K
=K
II
2000K
×K
I
2000K
=(4.40)2×5.31×10-10
Therefore, by reversing the reaction, we get reaction (iii) but at 2000K.
2CO(g)+O2(g)⇔2CO2(g), for which,
K
IV
2000K
=
1
K
III
2000K
=
1
4.402×5.31×10-10
=9.72×107
From reactions (iii) and (v), we see that as the temperature increases, the equilibrium constant decreases (9.72×107<2.24×1022). Reaction (iii) is this exothermic because ΔH will be negative.
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