Question

First law of thermodynamics and its limitations ​

Answer 1

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Limitations of First Law of Thermodynamics. First law does not provide a clear idea about thedirection of absorption or evolution of heat. The informations provided by the first law of thermodynamicsare not enough to predict thespontaneity or feasibility of a process.

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Answer 2

The first law of thermodynamics is a version of the law of conservation of energy, adapted for thermodynamic systems. The law of conservation of energy states that the total energy of an isolated system is constant; energy can be transformed from one form to another, but can be neither created nor destroyed..