first order reaction is 10
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A first order reaction is 10% complete in 20 min. The time taken for 19% completion is:
Answer-
For first order reaction:
Initially reaction is 10% complete, $$x=10;\ t=20 $$min
t=\dfrac{2.303}{k} log\dfrac{a}{a-x}t=
k
2.303
log
a−x
a
let a=100a=100
20 =\dfrac{2.303}{k} log\dfrac{100}{100-10}20=
k
2.303
log
100−10
100
20 =\dfrac{2.303}{k} \times 0.045320=
k
2.303
×0.0453
k = 0.1151 \times 0.0453 = 0.00521k=0.1151×0.0453=0.00521
Substituting the value of kk and x = 19x=19
t = \dfrac{2.303}{0.00521} log \dfrac{100}{100-19}t=
0.00521
2.303
log
100−19
100
t= 442.034 \times 0.09131 = 40.3 mint=442.034×0.09131=40.3min
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