first order reaction takes hundred minutes for completion of 60% of the reaction find the time when 90% of the reaction will be completed
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Answer:
251.41 min
Explanation:
Here Given,
t(1)= 100 min
t(2)= ?
First of all we should calculate the value of rate constant(k) for the 60% completion of the 1st order reaction.
Then put the value of 'k' for the 90% completion of the reaction and get the value of t(2).
We know,
for 60% completion of the 1st order reaction
k=(2.303÷t)×log(a÷a-x)
=>k= (2.303÷100)×log(100÷(100-60))
=>k= 9.16×10^-3 (unit)
then
for 90% completion of the 1st order reaction
k=(2.303÷t)×log(a÷a-x)
=>t= (2.303÷k)×log(a÷a-x)
=>t= (2.303÷9.16×10^-3)×log(100÷(100-90))
=>t= 251.41 min
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