For a first order reaction , tₐᵥ (average life time ) , t₅₀_% and t₇₅_% are in a order : * 1 point (A) t₅₀ < tₐᵥ < t₇₅ (B) t₅₀ < t₇₅< tₐᵥ (C) tₐᵥ
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Answer:
Correct option is
A
T
50
<T
av
<T
75
For first order reaction
T
50
=
k
0.693
T
av
=1.44×T
50
T
75
=
k
2.303
log
100−75
100
⟹
k
2.303
log4
⟹
k
2×0.693
=2×T
50
Hence T
50
<T
av
<T
75
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