Chemistry, asked by contactanweshar, 1 year ago

For a free expansion of an ideal gas in an isolated chamber which of the following statements is true ?
A. Entropy of the system increases
B. Temperature of the system decreases
C. Internal energy of the system decreases
D. Positive work is done by the system

Answers

Answered by JinKazama1
14
Final Answer :A Entropy of the system increases :

STEPS:
1) Free Expansion :
Irreversible Process in which gas Expands freely in Adiabatic Process.

Now,
A)
=> Since , Gas Expands Freely.
and Change in Entropy is proportional to
 ln( \frac{v(f)}{v(i)} )
Therefore, Entropy of the system increases.

B) Process is Adiabatic.
So,Niether Heat is released not absorbed.
=> del (Q) = 0
And,
Here, Gas Expands Freely without any External Pressure.
So, Work done by gas = 0
By First Law of Thermodynamic,
del(E) = del(Q) + W
= 0+ 0 =0
So,
Change in Internal Energy =0
=> del( T) = 0
=> T = constant

C) Internal Energy of the system remains constant as del(E) =0
=> E = constant

D) Workdone by the gas is 0 since there is no External Pressure.
Answered by kingofself
9

Answer:

(A)Entropy of the system increases.

Explanation:

  • The measure of disorder present in the system is called entropy.
  • It is low for solid state and very high for gaseous substances.
  • From the given, for a “free expansion” of an ‘ideal gas’ in an isolated chamber.
  • Means gas is transferred from chamber to free expansion.
  • It will leads to the increases the irregularity of the molecules than compared to the chamber.
  • Hence, the “entropy of the system increases”.
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