For adiabatic processes
Cp
A Α.
PV
constant
B
TV
constant
TV7-1
C
constant
D
TV
constant
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Adiabatic Process Revisited
In an adiabatic process, the First Law gives: dE = dW.
Use this result to determine adiabatic paths (adiabats) in the P-V diagram.
dE = dW → nCV dT = - P dV = - n RT dV/V.
→ CV dT/T = - R dV/V but R = (CP-CV).
dT/T = - (dV/V) [(CP-CV)/ CV].
→ d ln T = - (γ - 1) d ln V or d [ln T V (γ - 1)] = 0.
→ T V (γ - 1) = constant.
Equivalently use T ∝ PV to give P V γ = constant.
Note: adiabats are steeper than isotherms!
Adiabat: P V γ = const. or T V (γ - 1) = const.
Isotherm: P V = const.
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