Question

For an ideal solution, the correct option is :
(1) ∆ₘᵢₓ S = 0 at constant T and P
(2) ∆ₘᵢₓ V ≠ 0 at constant T and P
(3) ∆ₘᵢₓ H = 0 at constant T and P
(4) ∆ₘᵢₓ G = 0 at constant T and P

Answer 1

Answer:

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Explanation:

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Answer 2

For an ideal solution,  ∆ₘᵢₓ H = 0 at constant T and P

Explanation:

Ideal solution is a solution which obeys raoult's law at all conditions of temperature and pressure.

• For an ideal solution, There is no change in internal energy and also volume of the solution. i.e., $\Delta E =0, \Delta V=0$  

• Form Enthalpy equation, $\Delta H = \Delta E+P \Delta V$
• But, For an ideal solution $\Delta H=0$ Because $\Delta E =\Delta V = 0$
• Thus for an ideal solution, the following conditions obeyed.

1. $\Delta_{ mix} H = 0$ at constant T and P
2. ∆ₘᵢₓ S > 0 at constant T and P  
3. ∆ₘᵢₓ G < 0 at constant T and P
4. ∆ₘᵢₓ V = 0 at constant T and P