for aneline which is most contributing structure of its canonical forms
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In 3 (out of 5) resonance structures of aniline, the N atom has a positive charge and one of the C atoms or the ring (ortho or para to amino group) has a negative charge.
Hence, in the resonance hybrid for aniline, N atom has partial positive charge and C atoms or the ring (ortho or para to amino group) have partial negative charge.
Hence, aniline has dipole moment with the N−atom as the positive end.
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