For bromination on Benzene ring, Br2 is used in presence of FeCl3 but in case of bromination of aniline only
Br2 is used. Why?
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When benzene reacts with bromine under harsh conditions—liquid bromine, no solvent, and the Lewis acid FeBr3 as a catalyst—a reaction occurs in which one bromine is substituted for a ring hydrogen. (Because iron reacts with Br2 to give FeBr3, iron filings can be used in place of FeBr3.)
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