For d block: Group Number = Number of e − in (n−1)d subshell + number of e − in ns subshell explain with example
Answers
Answer:
For d block: Group Number = Number of e − in (n−1)d subshell + number of e − in ns subshell explain with example
Explanation:
Prediction of Period ⟶ In the electronic configuration of an atom, the principal quantum number (n) of the valence electrons represents the period of an element.
Prediction of Block ⟶ The orbital out of s,p,d and f which receives the last electron represents the block of an element
Prediction of Group ⟶ The group prediction occurs with the help of block as:-
(1) For s block: Group Number = Number of valence e
−
(2) For d block: Group Number = Number of e
−
in (n−1)d subshell + number of e
−
in ns subshell
(3) For p block: Group Number = Number of valence e
−
+10
(4) For f-block: Group Number = 3 (always)
For example for chlorine with Z=17
Electronic configuration = 1s
2
2s
2
2p
6
3s
2
3p
5
Since the last e
−
enters in p - subshell:
(i) ∴ Block will be
′
p
′
(ii) For group we have element in p-block
∴ Group number = 10+ Valence e
−
in s subshell + Valence e
−
in p subshell
Group Number = 10+2+5=17
(iii) For period
The quantum number of valence e
−
=3
∴ Period number = 3