For reducing one mole of Fe2+ ion to Fe the number of Faraday of electricity is
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Explanation:
Fe2+ /Fe acts as anode because its standard reduction potential is low i.e., oxidation occurs at this electrode and Fe3+/Fe acts as cathode because its standard reduction potential is high i.e., reduction occurs at this electrode.
∴Fe→Fe2++2e−(Anode)
and(Fe3++e−→Fe2+)×2(Cathode)Fe+2Fe3+→3Fe2+
Thus, if Fe2+, Fe3+and Fe blocks are kept together Fe3+ get reduced to Fe2+ i.e., concentration of Fe3+ decreases.
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