. For the following reaction at high pressure the relation of two rate constants (k1 for forward and k2 for revers) will be;
H2 + I2 <--------------------> 2HI
K1˃K2 b) K1˂ K2 c) K1=K2 d) pressure have no effect
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Applying the arhenius equation-
K=A[e
−
RT
E
a
]
Taking log both side
log
10
K=log
10
A−
2.303RT
E
a
log
10
K=log
10
10
13
−
2.303×8.314×600
240×10
3
log
10
K=13−
2.303×8.314×600
240×10
3
K=2.056×10
−8
S
−1
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