*For the process, NH₃ (g) + HCl (g) →NH₄Cl (s), which is right?*
1️⃣ ΔH > 0 ; ΔS > 0
2️⃣ ΔH < 0 ; ΔS > 0
3️⃣ ΔH > 0 ; ΔS < 0
4️⃣ ΔH < 0 ; ΔS < 0
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Answer:
For the reaction NH
4
Cl(S)→NH
3
(g)+HCl(g) at 25
0
C, enthalpy change △=+177kJmol
−1
and entropy change △S=+285JK
−1
mol
−1
. Calculate free energy change △G at 25
0
C and product whether the reaction is spontaneous or not.Given, △H=177 kJ/mol, △S=285 JK
−1
mol
−1
, T=298 K
Using the relation, △G=△H−T△S
△G=(177×10
3
J/mol)−(298 K)(285 JK
−1
mol
−1
)
△G=92070 J/mole
△G=92.07 kJ/mole
△G>0
Since △G is positive, Hence reaction is non spontaneous.
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