For the reaction, CO + 2H2 =CH3OH. If active mass of CO is kept constant and active mass of H2 is tripled, the rate of reaction will be
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active mass=no. of moles/concentration
Kc ={ch3oh}/{co}[H2]2
After tripling the active mass of H2,
conc=no. of moles/3.active mass
=[H2]/3
Kc' = [ch3oh]/[co][H2/3]2
=9.[ch3oh]/[co][H2]
Kc'=9Kc
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