For the reaction h2(g) + f2 (g) ⇌ 2hf(g) ; the energy of activation of forward reaction is 208 kJ mol^-1. energy of activation of backward reaction is
A) 328 kJ mol^-1
B) 744 kJ mol^-1
C) 536 kJ mol^-1
D) None of the above
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Answer:
ΔH=E
f
−E
b
−40=80−E
b
, E
b
=120kJ/mole
Catalyst lower the E
af
to 20kJ/mole for forward Rxn then E
f
′
=20kJ/mol
We know catalyst decreases the activation energy equal amount in both directions:
E
b
′
=(120−60)=60kj/mol
E
b
′
E
b
=
60
120
=2.0
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