formation on lindeman
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In chemical kinetics, the Lindemann mechanism, sometimes called the Lindemann-Hinshelwood mechanism, is a schematic reaction mechanism. Frederick Lindemann proposed the concept in 1922 and Cyril Hinshelwood developed it.
It breaks down an apparently unimolecular reaction into two elementary steps, with a rate constant for each elementary step. The rate law and rate equation for the entire reaction can be derived from the rate equations and rate constants for the two steps.
The Lindemann mechanism is used to model gas phase decomposition or isomerization reactions. Although the net formula for a decomposition or isomerization appears to be unimolecular and suggests first-order kinetics in the reactant, the Lindemann mechanism shows that the unimolecular reaction step is preceded by a bimolecular activation step so that the kinetics may actually be second-order in certain cases.
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