Forwhich value of "n" in HOOC−(CH2)n−COOH, only dehydration take place on heating?
Answers
Explanation:
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Only dehydration takes place on heating when the value of "n" is 2.
Given: Dicarboxylic acid of the form HOOC−(CH2)n−COOH
To Find: The value of "n" for which only dehydration takes place on heating
Solution:
1. Dehydration reaction involves the removal of water from the compound at a temperature of 573K which results in the formation of cyclic anhydrides.
2. Decarboxylation reaction involves the removal of carboxyl group and release of carbon dioxide gas on heating a compound.
3. Both dehydration and decarboxylation occur but it depends on the number of -(CH2)- groups in between the two carboxyl groups.
4. Dehydration reactions occur when there are 2 -(CH2)- groups in between the two carboxyl groups.
5. If there are more than 2 -(CH2)- groups in between the two carboxyl groups then decarboxylation reaction is preferred over dehydration.
Hence only dehydration takes place on heating when the value of "n" is 2.
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