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Fluorination of alkanes is highly exothermic which may explode. In order to prevent backward reaction, iodination of alkanes is carried in presence of oxidising agents like HgO or HIO3 or HIO3. ... The alkane is reactant and solvent, and this metal-free process provides a clean solution for their direct iodination
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Iodine does not react with the alkanes to any extent- at least,under normal lab conditions.
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Because there is no reaction in the dark.
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