give me the coupling reaction of diazonium salt
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The process of conversion of primary aromatic amines into its diazonium salt is called diazotization. Diazonium salts are important synthetic intermediates that can undergo coupling reactions to form azo dyes and electrophilic substitution reactions to introduce functional groups.
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The process of forming diazonium compounds is called "diazotation", "diazoniation", or "diazotization". The reaction was first reported by Peter Griess in 1858, who subsequently discovered several reactions of this new class of compounds. Most commonly, diazonium salts are prepared by treatment of aromatic amines with nitrous acid and additional acid. Usually the nitrous acid is generated in situ (in the same flask) from sodium nitrite and the excess mineral acid (usually aqueous HCl, H2SO4, p-H3CC6H4SO3H, or HBF4):
ArNH2 + HNO2 + HX → ArN2+X– + 2H2O
ArNH2 + HNO2 + HX → ArN2+X– + 2H2O
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