Give the diagrammatic representation of ETS and explain.
Answers
ᴀɴ ᴇʟᴇᴄᴛʀᴏɴ ᴛʀᴀɴꜱᴩᴏʀᴛ ꜱyꜱᴛᴇᴍ (ᴇᴛꜱ) ɪꜱ ᴀ ꜱᴇʀɪᴇꜱ ᴏꜰ ᴄᴏᴇɴᴢyᴍᴇꜱ ᴀɴᴅ ᴄyᴛᴏᴄʜʀᴏᴍᴇꜱ ᴡʜɪᴄʜ ᴛᴀᴋᴇ ᴩᴀʀᴛ ɪɴ ᴛʜᴇ ᴩᴀꜱꜱᴀɢᴇ ᴏꜰ ᴇʟᴇᴄᴛʀᴏɴꜱ ꜰʀᴏᴍ ᴀ ᴄʜᴇᴍɪᴄᴀʟ ᴛᴏ ɪᴛꜱ ᴜʟᴛɪᴍᴀᴛᴇ ᴀᴄᴄᴇᴩᴛᴏʀ.ᴛʜᴇ ᴩᴀꜱꜱᴀɢᴇ ᴏꜰ ᴇʟᴇᴄᴛʀᴏɴꜱ ꜰʀᴏᴍ ᴏɴᴇ ᴇɴᴢyᴍᴇ ᴏʀ ᴄyᴛᴏᴄʜʀᴏᴍᴇ ᴛᴏ ᴛʜᴇ ɴᴇxᴛ ɪꜱ ᴀᴄᴄᴏᴍᴩᴀɴɪᴇᴅ ᴡɪᴛʜ ᴛʜᴇ ʟᴏꜱꜱ ᴏꜰ ᴇɴᴇʀɢy ᴀᴛ ᴇᴀᴄʜ ꜱᴛᴇᴩ. ᴀᴛ ᴇᴀᴄʜ ꜱᴛᴇᴩ, ᴛʜᴇ ᴇʟᴇᴄᴛʀᴏɴ ᴄᴀʀʀɪᴇʀꜱ ɪɴᴄʟᴜᴅᴇ ꜰʟᴀᴠɪɴꜱ, ɪʀᴏɴ ꜱᴜʟᴩʜᴜʀ ᴄᴏᴍᴩʟᴇxᴇꜱ, qᴜɪɴᴏɴᴇꜱ ᴀɴᴅ ᴄyᴛᴏᴄʜʀᴏᴍᴇꜱ. ᴛʜᴇ ɪɴɴᴇʀ ᴍɪᴛᴏᴄʜᴏɴᴅʀɪᴀʟ ᴍᴇᴍʙʀᴀɴᴇ ᴩᴏꜱꜱᴇꜱꜱᴇꜱ ꜰɪᴠᴇ ᴄᴏᴍᴩʟᴇxᴇꜱ. ᴄᴏᴍᴩʟᴇx ᴠ ɪꜱ ᴄᴏɴᴄᴇʀɴᴇᴅ ᴡɪᴛʜ ᴀᴛᴩ ꜱyɴᴛʜᴇꜱɪꜱ. ᴄᴏᴍᴩʟᴇxᴇꜱ ɪ ᴛᴏ ɪᴠ ᴀʀᴇ ɪɴᴠᴏʟᴠᴇᴅ ɪɴ ᴇʟᴇᴄᴛʀᴏɴ ᴛʀᴀɴꜱᴩᴏʀᴛ. ᴛʜᴇꜱᴇ ᴄᴏᴍᴩʟᴇxᴇꜱ ᴀʀᴇ ᴀʀʀᴀɴɢᴇᴅ ɪɴ ᴀ ᴅᴇꜰɪɴɪᴛᴇ ꜱᴇqᴜᴇɴᴄᴇ ɪɴ ᴛʜᴇ ɪɴɴᴇʀ ᴍɪᴛᴏᴄʜᴏɴᴅʀɪᴀʟ ᴍᴇᴍʙʀᴀɴᴇ. ʀᴇᴅᴜᴄᴇᴅ ᴄᴏᴇɴᴢyᴍᴇꜱ ᴛʀᴀɴꜱꜰᴇʀ
ᴛʜᴇɪʀ ᴇʟᴇᴄᴛʀᴏɴꜱ ᴀɴᴅ ᴩʀᴏᴛᴏɴꜱ ᴛʜʀᴏᴜɢʜ ᴇᴛꜱ ɪɴ ᴛʜᴇ ꜰᴏʟʟᴏᴡɪɴɢ ᴍᴀɴɴᴇʀ:
ɪ. ᴛʀᴀɴꜱꜰᴇʀ ᴏꜰ ʜyᴅʀᴏɢᴇɴ ꜰʀᴏᴍ ɴᴀᴅʜ + ʜ+ ᴛᴏ ᴍᴇᴛᴀʟʟᴏꜰʟᴀᴠᴏᴩʀᴏᴛᴇɪɴ-ꜰᴍɴ (ꜰʟᴀᴠɪɴ ᴍᴏɴᴏɴᴜᴄʟᴇᴏᴛɪᴅᴇ). ꜰᴍɴ ɢᴇᴛꜱ ʀᴇᴅᴜᴄᴇᴅ ᴛᴏ ꜰᴍɴʜ2 ᴀɴᴅ ᴛʜᴇ ᴄᴏᴇɴᴢyᴍᴇ ɴᴀᴅʜ+ʜ+ ɢᴇᴛꜱ ᴏxɪᴅɪꜱᴇᴅ ᴛᴏ ɴᴀᴅ+. ᴏxɪᴅᴀᴛɪᴏɴ ᴏꜰ ɴᴀᴅʜ ᴏᴄᴄᴜʀꜱ ʙy ᴄᴏᴍᴩʟᴇx ɪ.
ɪɪ. ʀᴇᴅᴜᴄᴇᴅ ꜰᴍɴ (ɪ.ᴇ. ꜰᴍɴʜ2) ᴛʜᴇɴ ᴛʀᴀɴꜱꜰᴇʀꜱ ɪᴛꜱ ᴇʟᴇᴄᴛʀᴏɴꜱ ᴛᴏ ꜰᴇ–ꜱ ᴩʀᴏᴛᴇɪɴ (ɪʀᴏɴ ꜱᴜʟᴩʜᴜʀ ᴩʀᴏᴛᴇɪɴ) ᴀɴᴅ 2 ʜ+ ɪɴᴛᴏ ᴛʜᴇ ɪɴɴᴇʀ ᴍᴇᴍʙʀᴀɴᴇ ꜱᴩᴀᴄᴇ.
ɪɪɪ. ᴛʜᴇ ʀᴇᴅᴜᴄᴇᴅ ꜰᴇ–ꜱ ᴩʀᴏᴛᴇɪɴ ᴛʜᴇɴ ᴛʀᴀɴꜱꜰᴇʀꜱ ɪᴛꜱ ᴇʟᴇᴄᴛʀᴏɴꜱ ᴛᴏ ᴜʙɪqᴜɪɴᴏɴᴇ (ᴜq). ᴜq ᴛᴀᴋᴇꜱ ᴛᴡᴏ ᴇʟᴇᴄᴛʀᴏɴꜱ ꜰʀᴏᴍ ꜰᴇ–ꜱ ᴩʀᴏᴛᴇɪɴ ᴀɴᴅ ᴛᴡᴏ ᴩʀᴏᴛᴏɴꜱ (2 ʜ+) ꜰʀᴏᴍ ᴛʜᴇ ᴍᴀᴛʀɪx ᴛᴏ ʙᴇᴄᴏᴍᴇ ᴜqʜ2.
ɪᴠ. ʀᴇᴅᴜᴄᴇᴅ ᴜʙɪqᴜɪɴᴏɴᴇ (ᴜqʜ2) ᴛʜᴇɴ ᴛʀᴀɴꜱꜰᴇʀꜱ ɪᴛꜱ ᴇʟᴇᴄᴛʀᴏɴꜱ ᴛᴏ ᴄyᴛᴏᴄʜʀᴏᴍᴇ ʙ ᴀɴᴅ 2 ʜ+ ᴛᴏ ᴛʜᴇ ᴏᴛʜᴇʀ ꜱɪᴅᴇ ɪɴᴛᴏ ᴛʜᴇ ɪɴɴᴇʀ ᴍᴇᴍʙʀᴀɴᴇ ꜱᴩᴀᴄᴇ. ꜰᴀᴅʜ2 ʀᴇᴅᴜᴄᴇᴅ ɪɴ ᴛʜᴇ ᴋʀᴇʙꜱ ᴄyᴄʟᴇ ᴀʟꜱᴏ ᴇɴᴛᴇʀꜱ ᴛʜʀᴏᴜɢʜ ᴄᴏᴍᴩʟᴇx ɪɪ ɪɴᴛᴏ ᴇᴛꜱ ʙy ᴛʀᴀɴꜱꜰᴇʀʀɪɴɢ ɪᴛꜱ 2 ʜ ᴛᴏ ᴜq. ᴜq ɪꜱ ʀᴇᴅᴜᴄᴇᴅ ᴛᴏ ᴜqʜ2.
ᴠ. ɴᴀᴅʜ+ʜ+ ʀᴇᴅᴜᴄᴇᴅ ɪɴ ɢʟyᴄᴏʟyꜱɪꜱ ᴀʟꜱᴏ ᴇɴᴛᴇʀꜱ ᴇᴛꜱ. ɴᴀᴅʜ ʀᴇᴅᴜᴄᴇꜱ ᴀ ꜰʟᴀᴠᴏᴩʀᴏᴛᴇɪɴ-ᴄᴏɴᴛᴀɪɴɪɴɢ ɴᴀᴅʜ-ᴅᴇʜyᴅʀᴏɢᴇɴᴀꜱᴇ ʟᴏᴄᴀᴛᴇᴅ ᴏɴ ᴛʜᴇ ᴏᴜᴛᴇʀ ꜱᴜʀꜰᴀᴄᴇ ᴏꜰ ᴛʜᴇ ɪɴɴᴇʀ
ᴍɪᴛᴏᴄʜᴏɴᴅʀɪᴀʟ ᴍᴇᴍʙʀᴀɴᴇ.
ᴠɪ. ᴛʜᴇ ʀᴇᴅᴜᴄᴇᴅ ꜰʟᴀᴠᴏᴩʀᴏᴛᴇɪɴ (ꜰᴩʜ2) ᴛʜᴇɴ ᴇɴᴛᴇʀꜱ ᴛʜᴇ ᴍᴀɪɴ ᴩᴀᴛʜᴡᴀy ʙy ᴛʀᴀɴꜱꜰᴇʀʀɪɴɢ 2 ʜ
ᴛᴏ ᴜq. ᴛʜᴇ ʀᴇᴅᴜᴄᴇᴅ ᴜq ᴛʜᴇɴ ᴛʀᴀɴꜱꜰᴇʀꜱ ɪᴛꜱ ᴇʟᴇᴄᴛʀᴏɴꜱ ᴛᴏ ᴄᴏᴍᴩʟᴇx ɪɪɪ ᴀɴᴅ 2 ʜ+ ᴛᴏ ᴛʜᴇ
ᴏᴜᴛᴇʀ ꜱɪᴅᴇ.
ᴠɪɪ. ʀᴇᴅᴜᴄᴇᴅ ᴄyᴛᴏᴄʜʀᴏᴍᴇ ʙ ᴛʜᴇɴ ᴛʀᴀɴꜱꜰᴇʀꜱ ɪᴛꜱ ᴇʟᴇᴄᴛʀᴏɴꜱ ᴛᴏ ꜰᴇ–ꜱ ᴩʀᴏᴛᴇɪɴ. ᴛʜᴇ ꜰᴇ3+–ꜱ ɪꜱ ᴄᴏɴᴠᴇʀᴛᴇᴅ ᴛᴏ ꜰᴇ2+–ꜱ. ᴛʜɪꜱ ᴩʀᴏᴛᴇɪɴ ᴛʀᴀɴꜱꜰᴇʀꜱ ᴇʟᴇᴄᴛʀᴏɴꜱ ᴛᴏ ᴜq ᴡʜɪᴄʜ ᴀʟꜱᴏ ᴛᴀᴋᴇꜱ 2 ʜ+ꜰʀᴏᴍ ᴛʜᴇ ɪɴɴᴇʀ ᴍᴀᴛʀɪx ᴛᴏ ʙᴇᴄᴏᴍᴇ ᴜqʜ2.
ᴠɪɪɪ. ᴛʜᴇ ʀᴇᴅᴜᴄᴇᴅ ᴜq (ɪ.ᴇ. ᴜqʜ2) ᴛʀᴀɴꜱꜰᴇʀꜱ ɪᴛꜱ ᴇʟᴇᴄᴛʀᴏɴꜱ ᴛᴏ ᴄyᴛᴏᴄʜʀᴏᴍᴇ ᴄ1 ᴀɴᴅ ᴀ ᴛʜɪʀᴅ ᴩᴀɪʀ ᴏꜰ ʜ+ ɪꜱ ᴛʀᴀɴꜱᴩᴏʀᴛᴇᴅ ᴏᴜᴛᴡᴀʀᴅʟy.
ɪx. ʀᴇᴅᴜᴄᴇᴅ ᴄyᴛᴏᴄʜʀᴏᴍᴇ ᴄ1 ᴛʜᴇɴ ʀᴇᴅᴜᴄᴇꜱ ᴄyᴛᴏᴄʜʀᴏᴍᴇ ᴄ ʙy ᴛʀᴀɴꜱꜰᴇʀʀɪɴɢ ɪᴛꜱ ᴇʟᴇᴄᴛʀᴏɴꜱ.
x. ᴛʜᴇ ᴇʟᴇᴄᴛʀᴏɴꜱ ꜰʀᴏᴍ ᴄyᴛᴏᴄʜʀᴏᴍᴇ ᴄ ᴀʀᴇ ᴛʜᴇɴ ᴛʀᴀɴꜱꜰᴇʀʀᴇᴅ ᴛᴏ ᴏ2 ᴠɪᴀ ᴄyᴛ ᴀ ᴀɴᴅ ᴄyᴛ ᴀ3.
Answer:
Give the diagrammatic representation of ETS and explain.
Explanation:
Give the diagrammatic representation of ETS and explain.
refer to the above Picture
