Question

Give the IUPAC name of Na4[Fe(CN)5NOS].

Answer 1

The IUPAC name of Na4[Fe(CN)5NOS] is

Sodium pentacyanonitrosylferrate(II)

Answer 2

IUPAC name of compound $Na_4[Fe(CN)_5NOS$ is Sodiumpentacyanonitrosylthiolferrate (II).

Explanation:

• The following steps must be followed to write the IUPAC name of coordination compounds:

1. The name of the ligand and metal ion must be first written.
2. The neutral ligand must be written first, followed by the negative and lastly the positive one must be written.
3. In the case of more than one ligand, alphabetical order must be used.
4. The suffix "-ido" must be added to the names of the anions.
5. The central atom must be named and oxidation number must be calculated.

• Thus according to the above-given steps, the IUPAC name of the compound $Na_4[Fe(CN)_5NOS$ is identified as Sodiumpentacyanonitrosylthiolferrate (II).

Learn more about writing IUPAC name of the coordination compound

Write the IUPAC name of [Co(NH3)6]Cl3

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Write the IUPAC names of the following coordination compounds: (i) [Co(NH3)6]Cl3 (ii) [Co(NH3)5Cl]Cl2 (iii) K3[Fe(CN)6] (iv) K3[Fe(C2O4)3] (v) K2[PdCl4] (vi) [Pt(NH3)2Cl(NH2CH3)]Cl

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