> Q. 10) Detgermine weather the reaction will be spontaneous or nonspontaneous uder standard
conditions. Zn + Cu* → Zn** + Cu AH'=--219 KJ AS =-21 JK
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Answer:
2A(g) + B(g) -------> 2D(g) : ΔU° = -10.5 KJ
Δng = np - nr
= 2 - (2 + 1) = 2 - 3 = -1
ΔH° = ΔU° + ΔΔngRT, from formula,
= -10.5 KJ + (-1) × 0.008314 KJ/K/mol × 298K
=-10.5 KJ - 2.447 KJ
= -12.947 KJ
now, use the formula, ΔG° = ΔH° - TΔS°
= -12.947 KJ - 298K × (-44 × 10⁻³ J/K)
= -12.947 KJ + 13.14 KJ
= +0.165 KJ
the reaction will not occur spontanteously because ΔG° is positive.
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